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Production of Octane-Enhancing Oxygenates Because of legislative actions to improve gasoline quality, alkenes and aromatics content of motor gasoline will be limited, requiring additional sources of octane enhancing components 60 ,6l Besides alkylation and isomerization to yield highly branched (high-octane) hydrocarbons, oxygenate additives are the most important way to satisfy these requirements 62- 64 The most important gasoline octane enhancer is tert-butyl methyl ether (MTBE)65-67 (see, however, a discussion in Section 182 of the controversy about its use) MTBE is manufactured by the acid-catalyzed addition of methanol to isobutylene 68 ,69 The main source of isobutylene is FCC C4 cuts, a mixture of isomeric butylenes Isobutylene can originate from dehydration of tert-butyl alcohol a major byproduct of propylene oxide manufacture,7o and from dehydrogenation of isobutane7l (see Section 233) The addition of methanol to isobutylene is catalyzed by an acidic ion-exchange resin.

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manganese complexes (4).142 Wacker oxidation of various alkenes to the corresponding ketones was developed using tert-BuOOH in the presence of catalyst 5 bearing perfluorinated ligands. 144

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Preheated methanol and isobutylene-containing C4 fraction freed from 1,3-butadiene are fed to a reactor at a pressure of 20 atm The temperature is kept below 120 C Since the reaction is exothermic, this may require cooling, depending on the initial isobutylene concentration in the feed Single- or two-stage processes are employed; the latter allow isobutylene conversions better than 99% Since linear butene isomers are unreactive under these operating conditions, high selectivities are achieved Over the years several technological variations were introduced to make the process more economical (particularly the separation of methyl alcohol from MTBE forming an azeotropic mixture)72-75 Other ethers such as tert-butyl ethyl ether (ETBE) and tert-amyl methyl ether (TAME) are manufactured similarly from ethanol and isobutylene, and methanol and isoamylenes, respectively74-77 Etherification of the entire light FCC gasoline (C 4-C7 branched olefins) was also suggested.

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The concept of channels in Limbo are descended from Hoare's Communicating Sequential Processes (CSP) [25]. Calculi for reasoning about concurrent systems include Milner's CCS [39] and 7r-calculus [41, 70], a good introduction to these ideas being [40]. An early language that incorporated ideas from CSP is Occam [37, 38], which run on the Inmos Transputers [36]. The concept of constructing applications as filters acting on streams of data is familiar in other languages [2]. A lucid description that is closely related to Limbo through Pike's Newsqueak [50] is [33].

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78 Octane numbers of higher ethers decrease more steeply than do those of the corresponding alkenes, and thus the gain in octane numbers is not significant Such a process, however, improves gasoline quality by decreasing olefin content and vapor pressure A new catalyst to transform branched alkenes in FCC naphtha fraction to a mixture of methyl ethers has been introduced by Erdolchemie79 and BP (Etherol process)80 A palladium-on-cation-exchange resin catalyst promotes.

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between various motionless mixers. On a simple pressure drop basis it is a tradeoff between length needed to get to a certain quality of mixing versus the required pressure drop. This balance can be determined by using the data in the earlier tables. Usually, the device with the smallest KL is the one with the lowest pressure drop but the longest length. Then the investment must be looked at. Longer mixers cost more. In some cases the extra length required to obtain a certain CoV is not possible due to space limitations, and shorter mixers operating with higher pressure drop are preferred. When the viscosity ratio of the main stream to the additive stream is large (greater than 100), only the SMX and KMX have been demonstrated to be effective.

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